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George started using a 3 pickup Danelectro/Coral Scorpion 12-string Guitar sometime towards the mid 1970's, It may have been under another brand name only availible outside the USA though. It's visible in the music video for "Instant Poetry" and probably used on the Switch album in 1975 as well. I have also seen Barry Hay (lead singer) use this guitar around that time as well.
This is an incredibly rare guitar and hard to find a good picture of online. What determined that this was a D3N12 scorpion is that it has no vibrato and three pickups, rather than the more common 2 pickup model hardtail, or the three pickup model with a vibrato.
Here's a picture of George with it in the 70's - http://iv1.lisimg.com/image/9693902/250full-george-kooymans.jpg
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